The Hubble Space Telescope has devoted 500 orbits to observing 250 massive stars with low metallicity in the ultraviolet (UV) range within the framework of the ULLYSES program. The X-Shooting ULLYSES (XShootU) project enhances the legacy value of this UV dataset by providing high-quality optical and near-infrared spectra, which are acquired using the wide-wavelength- coverage X-shooter spectrograph at ESO's Very Large Telescope. XShootU emphasises the importance of combining UV with optical spectra for the consistent determination of key stellar parameters such as effective temperature, surface gravity, luminosity, abundances, and wind characteristics including mass-loss rates as a function of metallicity. Since uncertainties in these parameters have implications across various branches of astrophysics, the data and modelling generated by the XShootU project are poised to significantly advance our understanding of massive stars at low metallicity. This is particularly crucial for confidently interpreting James Webb Space Telescope (JWST) data of the earliest stellar generations, making XShootU a unique resource for comprehending individual spectra of low-metallicity stars.

One of the largest surprises from the LIGO results regarding the first gravitational wave detection (GW 150914) was the fact the black holes (BHs) were heavy, of order 30 - 40 M<SUB>⊙</SUB>. The most promising explanation for this obesity is that the BH-BH merger occurred at low metallicity (Z): when the iron (Fe) contents is lower this is expected to result in weaker mass loss during the Wolf-Rayet (WR) phase. We therefore critically evaluate the claims for the reasons of heavy BHs as a function of Z in the literature. Furthermore, weaker stellar winds might lead to more rapid stellar rotation, allowing WR and BH progenitor evolution in a chemically homogeneous manner. However, there is as yet no empirical evidence for more rapid rotation amongst WR stars in the low Z environment of the Magellanic Clouds. Due to the intrinsic challenge of determining WR rotation rates from emission lines, the most promising avenue to constrain rotation-rate distributions amongst various WR subgroups is through the utilisation of their emission lines in polarised light. We thus provide an overview of linear spectro-polarimetry observations of both single and binary WRs in the Galaxy, as well as the Large and Small Magellanic Clouds, at 50% and 20% of solar Z, respectively. Initial results suggest that the route of chemically homogeneous evolution (CHE) through stellar rotation is challenging, whilst the alternative of a post-LBV or common envelope evolution is more likely.

Understanding the complex behavior of High Mass X-ray binaries (HMXBs) is not possible without detailed information about their donor stars. While crucial, this turns out to be a challenge on multiple fronts. First, multi-wavelength spectroscopy is vital. As such systems can be highly absorbed, this is often already hard to accomplish. Secondly, even if the spectroscopic data is available, the determination of reliable stellar parameters requires sophisticated model atmospheres that accurately describe the outermost layers and the wind of the donor star.

Classical Wolf-Rayet (WR) stars mark an important stage in the late evolution of massive stars. As hydrogen-poor massive stars, these objects have lost their outer layers, while still losing further mass through strong winds indicated by their prominent emission line spectra. Wolf-Rayet stars have been detected in a variety of different galaxies. Their strong winds are a major ingredient of stellar evolution and population synthesis models. Yet, a coherent theoretical picture of their strong mass-loss is only starting to emerge. In particular, the occurrence of WR stars as a function of metallicity (Z) is still far from being understood.